71989-18-9

71989-18-9Fmoc-Glu(OtBu)-OH

中文名称:Fmoc-O-叔丁基-L-谷氨酸 
英文名称:Fmoc-L-glutamic acid 5-tert-butyl ester
英文同义词:N-ALPHA-FMOC-L-GLUTAMIC ACID GAMMA-T-BUTYL ESTER;N-ALPHA-FMOC-L-GLUTAMIC ACID GAMMA-TERT-BUTYL ESTER;N-9-FLUORENYLMETHYLOXYCARBONYL-L-GLUTAMIC ACID GAMMA-T-BUTYL ESTER;N-9-FLUORENYLMETHYLOXYCARBONYL-L-GLUTAMIC ACID GAMMA-TERT-BUTYL ESTER;N-ALPHA-(9-FLUORENYLMETHYLOXYCARBONYL)-L-GLUTAMIC-ACID-GAMMA-T-BUTYL ESTER;N-ALPHA-(9-FLUORENYLMETHOXYCARBONYL)-GAMMA-T-BUTYL-L-GLUTAMIC ACID;N-FMOC-L-GLUTAMIC ACID GAMMA-T-BUTYL ESTER;N-FMOC-O-T-BUTYL-L-GLU
CAS号:71989-18-9
分子式:C24H27NO6
分子量:425.47
熔点 83-90 °C
比旋光度 -4.5 ? (c=1, 80% acetic acid)
折射率 -4 ° (C=1, 80% AcOH)
储存条件 2-8°C
化学性质 ：白色结晶或结晶性粉末；溶于乙酸乙酯、乙酸和DMF，不溶于石油醚； mp为88-90℃；比旋光度[α]20D-13.5°--15.5°(0.5-2 mg/ml，DMF)，[α]20D+8°(0.5-2mg/ml，乙酸乙酯)，[α]20D-4°(0.5-2 mg/ml，80%乙酸)。
用途 ：用作氨基酸保护单体，用于多肽合成。
生产方法 以芴甲氧羰基氯(或叠氮)和L-谷氨酸-5-叔丁酯为原料，碱性条件下进行酰化反应，经结晶纯化后得产品。  

00770 Fmoc-D-Glu(OtBu)-OH/104091-08-9
01218 Fmoc-lle-OH/71989-23-6
01217 Fmoc-D-lle-OH/143688-83-9
01439Fmoc-Lys(2-Cl-Z)-OH/133970-31-7
01437Fmoc-Lys(Boc)-OH/71989-26-9
01436Fmoc-D-Lys(Boc)-OH/ 92122-45-7
01450Fmoc-Lys(Z)-OH/86060-82-4 
01510Fmoc-D-Met-OH/112883-40-6
01710Fmoc-D-Pro-OH/101555-62-8
01819Fmoc-Ser-OH/73724-45-5
01820Fmoc-Ser(Bzl)-OH/83792-48-7
01915 Fmoc-Thr-OH?H2O/73731-37-0
01916Fmoc-Thr(Bzl)-OH/117872-75-0
02015Fmoc-Trp-OH/35737-15-6
02014Fmoc-D-Trp-OH/86123-11-7
02191  Fmoc-Tyr(Bzl)-OH/71989-40-7
08716Fmoc-Orn(Boc)-OH/109425-55-0
01821Fmoc-D-Ser(tBu)-OH/128107-47-1
Fmoc-His(Tos)-OH

00106 Boc-Ala-OH15761-38-3
00105Boc-D-Ala-OH 7764-95-6
00138Boc-MeAla-OH 16948-16-6
00406Boc-Asp-OH 13726-67-5
00412Boc-Asp(OBzl)-OH7536-58-5
00623Boc-Cys(Trt)-OH21947-98-8
00903Boc-Gly-OH 4530-20-5
01418Boc-Lys(Fmoc)-OH 84624-27-1
01804Boc-D-Ser-OH 6368-20-3
01908Boc-Thr-OH2592-18-9
02007Boc-D-Trp-OH 5241-64-5
06105Boc-Har-OH.HCl 128719-65-3
07904Boc-Tle-OH 62965-35-9
08605Boc-Nva-OH 53308-95-5
15204Boc-L-Phe(4-I)-OH62129-44-6
16105Boc-D-4-NO2-Phe-OH61280-75-9
01608Boc-D-Phe-OH 18942-49-9
01305Boc-D-Leu-OH.H2O16937-99-8
01424Boc-Lys(Z)-OH 2389-45-9
21504Boc-L-Cyclopentylglycine109183-72-4
11204Boc-L-4-Br-Phe-OH62129-39-9
00212Boc-Arg(NO2)-OH/2188-18-3
00211Boc-D-Arg(NO2)-OH/50913-12-7
01118Boc-Hyp-Ome/74844-91-0
00206Boc-D-Arg-OH?HCl?H2O/114622-81-0
00207Boc-Arg-OH?HCl?H2O/35897-34-8
00310Boc-Asn(Trt)-OH/132388-68-2
00405Boc-D-Asp-OH/62396-48-9
00621Boc-Cys(Bzl)-OH/5068-28-0
00714Boc-Glu(OBzl)-OH/13574-13-5
01006Boc-His-OH/17791-52-5
01306Boc-Leu-OH?H2O/13139-15-6
01305Boc-D-Leu-OH?H2O/16937-99-8
01416Boc-Lys(Boc)-OH?DCHA/15098-69-8
01418Boc-Lys(Fmoc)-OH/84624-27-1
014167Boc-D-Lys(Fmoc)-OH/ 115186-31-7
01424Boc-Lys(Z)-OH/2389-45-9
01506Boc-Met-OH/2488-15-5
08712Boc-Orn(Z)-OH/2480-93-5
01609Boc-Phe-OH/13734-34-4
01706Boc-Pro-OH/15761-39-4
01805Boc-Ser-OH/3262-72-4
01810Boc-Ser-Ome/2766-43-0
01808Boc-Ser-Obzl/59524-02-6
01813  Boc-Ser(Bzl)-OH/23680-31-1
01911Boc-Thr(Bzl)-OH/15260-10-3
02008Boc-Trp-OH/13193-14-5
02108Boc-Tyr-OH/3978-80-1
02112Boc-Tyr(Bzl)-OH/2130-96-3
02207Boc-Val-OH/13734-41-3
01027Boc-His(Tos)-OH/35899-43-5
00214Boc-Arg(Tos)-OH/13836-37-8
Boc-Cys(pMeOBzl)-OH
Boc-Glu(OcHex)-OH

01714 Z-Pro-OH  1148-11-4
01826 Z-D-Ser-OH 6081-61-4
02309   Z-Beta-Ala-OH 2304-94-1
01224Z-lle-OH 3160-59-6
01621Z-Phe-OH1161-13-3
02223   Z-Val-NCA158257-41-1
09708Z-D-Phg-OH 17609-52-8
09709Z-Phg-OH53990-33-3
00117  Z-Ala-OH/1142-20-7
00118Z-D-Ala-OH/26607-51-2
02309Z-β-Ala-OH/2304-94-1
00230Z-Arg-OH/1234-35-1
00229Z-Arg-OH?HCl/56672-63-0
00325  Z-Asn-OH/2304-96-3
00327  Z-Asn(Trt)-OH/132388-57-9
00426  Z-Asp-OH/1152-61-0
00433  Z-Asp(OBzl)-OH/3479-47-8
00639  Z-Cys(Bzl)-OH/3257-18-9
00741  Z-Glu-OH/1155-62-0
00744  Z-Glu(OBzl)-OH/5680-86-4
00818  Z-Gln-OH/2650-64-8
00911  Z-Gly-OH/1138-80-3
01235  Z-Ile-OH.DCHA/26699-00-3
01316  Z-Leu-OH/2018-66-8
01480  Z-Lys(Boc)-OH.DCHA/2212-76-2
01620  Z-D-Phe-OH/2448-45-5
01713  Z-D-Pro-OH/6404-31-5
01827  Z-Ser-OH/1145-80-8
01848  Z-DL-Ser-OH/2768-56-1
01829  Z-Ser-Ome/1676-81-9
01830  Z-Ser(Bzl)-OH/20806-43-3
01832  Z-Ser(tBu)-OH/1676-75-1
01921  Z-Thr-OH/19728-63-3
01926  Z-Thr(Bzl)-OH/69863-36-1
02018  Z-D-Trp-OH/2279-15-4
02219  Z-Val-OH/1149-26-4
02218  Z-D-Val-OH/1685-33-2
Z-Asp(OBzl)-OBzl
Z-Cys(Trt)-OH